domingo, 4 de abril de 2021

Thermodynamics fundamentals

 Recently I have been reading Principles of extractive metallurgy , I'm currently at the starting chapters, mostly thermodynamics review. I will create an entry for every chapter with a couple of solved problems. 

So for this week these are the exercises:

1) For the reaction $H_2\text{(g, 1 atm)}+\frac{1}{2}O_2\text{(g, 1 atm)}=H_2O\text{(l)}$, $\Delta H^{\circ}_{298}=-285.9$ kJ and $\Delta G^{\circ}_{298}=-238$ kJ.

a) Compute $\Delta S^{\circ}_{298}$

b) The reaction can proceed at 298 K and 1 atm in a reversible way, for example, in a fuel cell, or in a completely irreversible form, that is, by combustion with no other work besides volume. Compute for both cases the heat $q$ absorbed from the environment and, for case a), the work $w'$ done on the environment. Show that your results are in agreement with the second law of thermodynamics.

Now I will try using a jupyter notebook for storing the solutions, I think the possibility of combining text and code could be useful for problems that requires several calculations.

The solution can be found here.

 

 

 

 

 

 

 

 

 

 





No hay comentarios:

Publicar un comentario

Starting with IDAES: Steady state CSTR